How to choose the different types of
phosphating process
According to the operating temperature, can be
divided into high-temperature phosphating, medium-temperature phosphating,
low-temperature phosphating.
1) low-temperature phosphating, at room
temperature, long processing time, in addition to medium-temperature
phosphating has been added to the composition, in order to accelerate the speed
of phosphating, but also add fluoride, the advantage of low-temperature work,
without heating. The solution is stable mud slag less, but the film corrosion
resistance is poor, bonding, heat resistance is also poor, the processing time
is long. This phosphate in the production of not much application, spray
phosphating when applied.
2) medium-temperature phosphating 50 to
70 ℃, with Ma Zhifu salt, zinc dihydrogen phosphate and oxidizing agents (such
as zinc nitrate, manganese nitrate, nickel nitrate) composed of phosphating
solution, the film in addition to iron, manganese and other ferrous metals, but
also interspersed with zinc, nickel. Film corrosion resistance, bonding and
high-temperature phosphate film equivalent, stable solution, film speed, slag
less than high-temperature phosphating. This process is applicable to a large
area, in addition to the lower requirements for the hardness of the functional
phosphate film, phosphating before painting the most applications. The
disadvantage is that the composition of high-temperature phosphate is more
complex, difficult to adjust.
3) high-temperature phosphate treatment
temperature of 90 to 98 ℃, with Ma Zhifu salt and oxidizer (such as manganese
nitrate) phosphate solution, phosphate film for iron, manganese, does not
contain zinc. Film corrosion resistance, bonding, heat resistance, hardness are
relatively high. The disadvantage is the long heating time, energy consumption,
the amount of slag. Composition changes quickly, the solution is not stable.
Phosphate crystallization coarse, thick film. This process is suitable for
functional phosphate film, such as gears, automotive piston rings with friction
reduction layer, lubrication phosphate layer between processing processes.
In summary, medium-temperature
phosphating is the most promising process, in addition to the requirement that
the phosphate film can not contain zinc components outside the parts, can be
applied to most products in phosphate production, especially the use of
phosphate filter so that the medium-temperature phosphate film more fine,
inclusions and adsorption reduced, more suitable for pre-painting or some of
the phosphate film requirements on a particularly fine product.
Most of the phosphating solutions sold on
the market in recent years belong to this type of process. Certain phosphating
solution in the oxidizer used organic oxide, organic oxide decomposition has a
certain time, is the life of the organic oxide. In the life of the oxide to
generate phosphate film, outside the life of the organic oxide, phosphate
reaction basically stopped. This reduces the consumption of other components of
the phosphate solution, the amount of slag is greatly reduced. And the analysis
can be grasped by the oxidant content, the appropriate supplement for the
situation.
According to the operating temperature,
can be divided into high-temperature phosphating, medium-temperature
phosphating, low-temperature phosphating.
1) low-temperature phosphating, at room
temperature, long processing time, in addition to medium-temperature
phosphating has been added to the composition, in order to accelerate the speed
of phosphating, but also adding fluoride, the advantage of low-temperature
work, without heating. The solution is stable mud slag less, but the film
corrosion resistance is poor, bonding, heat resistance is also poor, the
processing time is long. This kind of phosphating in production is not much,
spray phosphating when applied.
2) medium-temperature phosphating 50 to
70 ℃, with Ma Zhifu salt, zinc dihydrogen phosphate and oxidizing agents (such
as zinc nitrate, manganese nitrate, nickel nitrate) composed of phosphating
solution, the film in addition to iron, manganese and other ferrous metals, but
also interspersed with zinc, nickel. Film corrosion resistance, bonding and
high-temperature phosphate film equivalent, stable solution, film speed, slag
less than high-temperature phosphating. This process is applicable to a large
area, in addition to the lower requirements for the hardness of the functional
phosphate film, phosphating before painting the most applications. The
disadvantage is that the composition of high-temperature phosphate is more
complex, difficult to adjust.
3) high-temperature phosphate treatment
temperature of 90 to 98 ℃, with Ma Zhifu salt and oxidizer (such as manganese
nitrate) phosphate solution, phosphate film for iron, manganese, does not
contain zinc. Film corrosion resistance, bonding, heat resistance, hardness are
relatively high. The disadvantage is the long heating time, energy consumption,
the amount of slag. Composition changes quickly, the solution is not stable.
Phosphate crystallization coarse, thick film. This process is suitable for
functional phosphate film, such as gears, automotive piston rings with friction
reduction layer, lubrication phosphate layer between processing processes.
In summary, medium-temperature
phosphating is the most promising process, in addition to the requirement that
the phosphate film can not contain zinc components outside the parts, can be
applied to most products in phosphate production, especially the use of
phosphate filter so that the medium-temperature phosphate film more fine,
inclusions and adsorption reduced, more suitable for pre-painting or some of
the phosphate film requirements on a particularly fine product.
Most of the phosphating solutions sold on
the market in recent years belong to this type of process. Certain phosphating
solution in the oxidizer used organic oxide, organic oxide decomposition has a
certain time, is the life of the organic oxide. In the life of the oxide to
generate phosphate film, outside the life of the organic oxide, phosphate
reaction basically stopped. This reduces the consumption of other components of
the phosphate solution, the amount of slag is greatly reduced. And the analysis
can be grasped by the oxidant content, the appropriate supplement for the
situation.
According to the operating temperature,
can be divided into high-temperature phosphating, medium-temperature
phosphating, low-temperature phosphating.
1) low-temperature phosphating, at room
temperature, long processing time, in addition to medium-temperature
phosphating has been added to the composition, in order to accelerate the speed
of phosphating, but also adding fluoride, the advantage of low-temperature
work, without heating. The solution is stable mud slag less, but the film
corrosion resistance is poor, bonding, heat resistance is also poor, the
processing time is long. This kind of phosphating in production is not much,
spray phosphating when applied.
2) medium-temperature phosphating 50 to
70 ℃, with Ma Zhifu salt, zinc dihydrogen phosphate and oxidizing agents (such
as zinc nitrate, manganese nitrate, nickel nitrate) composed of phosphating
solution, the film in addition to iron, manganese and other ferrous metals, but
also interspersed with zinc, nickel. Film corrosion resistance, bonding and
high-temperature phosphate film equivalent, stable solution, film speed, slag
less than high-temperature phosphating. This process is applicable to a large
area, in addition to the lower requirements for the hardness of the functional
phosphate film, phosphating before painting the most applications. The
disadvantage is that the composition of high-temperature phosphate is more
complex, difficult to adjust.
3) high-temperature phosphate treatment
temperature of 90 to 98 ℃, with Ma Zhifu salt and oxidizer (such as manganese
nitrate) phosphate solution, phosphate film for iron, manganese, does not
contain zinc. Film corrosion resistance, bonding, heat resistance, hardness are
relatively high. The disadvantage is the long heating time, energy consumption,
the amount of slag. Composition changes quickly, the solution is not stable.
Phosphate crystallization coarse, thick film. This process is suitable for
functional phosphate film, such as gears, automotive piston rings with friction
reduction layer, lubrication phosphate layer between processing processes.
In summary, medium-temperature
phosphating is the most promising process, in addition to the requirement that
the phosphate film can not contain zinc components outside the parts, can be
applied to most products in phosphate production, especially the use of
phosphate filter so that the medium-temperature phosphate film more fine,
inclusions and adsorption reduced, more suitable for pre-painting or some of
the phosphate film requirements on a particularly fine product.
Most of the phosphating solutions sold on
the market in recent years belong to this type of process. Certain phosphating
solution in the oxidizer used organic oxide, organic oxide decomposition has a
certain time, is the life of the organic oxide. In the life of the oxide to
generate phosphate film, outside the life of the organic oxide, phosphate
reaction basically stopped. This reduces the consumption of other components of
the phosphate solution, the amount of slag is greatly reduced. And through the
analysis can grasp the content of the oxidizer, the appropriate supplement for
the situation.